Electronic spectra and structure of the hydrogen halides: Characterization of the electronic structures of HBr and DBr lying between 79 500 and 83 900 cm−1 above X1Σ+期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Electronic spectra and structure of the hydrogen halides: Characterization of the electronic structures of HBr and DBr lying between 79 500 and 83 900 cm⁻¹ above X¹Σ⁺

Authors:	Dorothy S Ginter Marshall L Ginter Shelby G Tilford

Institution:	Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742 USA;National Aeronautics and Space Administration Headquarters, Washington, D. C. 20546 USA

Abstract:	The high-resolution absorption spectra of HBr and DBr were reinvestigated in the 1258-Å (79 500 cm^?1) to 1192-Å (83 900 cm^?1) region. This spectral region was found to contain bands attributable to (1) V¹Σ⁺-X¹Σ⁺(v′ - 0) with v′ > 0, (2) (v′ - 0) transitions with v′ > 0 from X¹Σ⁺(v″ = 0) to states associated with the (σ²π³)cπ and (σ²π³)cσ configurations, and (3) (v′ - 0) transitions with $v′ ≧ 0$ from X¹Σ⁺(v″ = 0) to states associated with the previously unreported configurations (σ²π³)dσ, dπ, aδ, eσ, and fσ.

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