Analysis of the 2770-Å emission system in I2 |
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Authors: | KS Viswanathan Abha Sur Joel Tellinghuisen |
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Institution: | Department of Chemistry, Vanderbilt University, Nashville, Tennessee 37235 USA |
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Abstract: | A weak emission spectrum of I2 near 2770 Å is reanalyzed and found to to minate on the A(1u3Π) state. The assigned bands span v″ levels 5–19 and v′ levels 0–8. The new assignment is corroborated by isotope shifts, band profile simulations, and Franck-Condon calculations. The excited state is an ion-pair state, probably the 1g state which tends toward . In combination with other results for the A state, the analysis yields the following spectroscopic constants: T″e = 10 907 cm?1, ″e = 1640 cm?1, ω″e = 95 cm?1, ; T′e = 47 559.1 cm?1, ω′e = 106.60 cm?1, . |
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