Synthesis of phosphorescent iridium-containing acrylic monomers and their room-temperature polymerization by Cu(0)-RDRP |
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Authors: | Cheyenne J Christopherson Zoë S Hackett Ethan R Sauvé Nathan R Paisley Christopher M Tonge Don M Mayder Zachary M Hudson |
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Institution: | Department of Chemistry, The University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, V6T 1Z1 Canada |
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Abstract: | A series of acrylic monomers based on cyclometalated iridium(III) complexes have been synthesized based on common phosphorescent emitters for organic light-emitting diodes. A simple room-temperature polymerization procedure for these materials was developed using Cu(0) reversible deactivation radical polymerization, providing polymers with low dispersities of 1.08–1.14 at conversions from 81 to 93% when the Ir complexes are copolymerized with a carbazole-based acrylic host. These methods were also found to be suitable for the preparation of high-molecular-weight polymers with M n approaching 40,000 Da, as well as block copolymers formed in one pot from the chain extension of methyl acrylate. This scalable room-temperature synthesis of iridium-containing copolymers and block copolymers provides a useful route to optoelectronic materials, which we anticipate can be readily adapted to a broad range of acrylic metallopolymers. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 2539–2546 |
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Keywords: | block copolymer carbazole host copolymerization Cu(0)-RDRP iridium copolymer living polymerization metallopolymer |
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