Electron-impact induced hydrogen scrambling in cyclohexanol and methylcyclohexanols |
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| Authors: | Robert H. Shapiro Steven P. Levine A. M. Duffield |
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| Affiliation: | 1. Department of Chemistry, University of Colorado, Boulder, Colorado 80302, USA;2. Department of Chemistry, Stanford University, Stanford, California 94305, USA |
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| Abstract: | Exact mass measurements and the mass spectral behavior of O-deuterated cyclohexanols, coupled with a re-evaluation of previously published data1,2, show that the hydrogen attached to oxygen undergoes partial scrambling with the 2, 3, 5 and 6 position ring hydrogens prior to or during the formation of the major primary fragment ions. |
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