Études calorimétriques en milieu solvant organique IV. Dissociation de LiAlH4 dans le tétrahydrofuranne |
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| Authors: | Pierre Claudy Bernard Bonnetot Daniel Mathurin Guy Turck |
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| Institution: | Laboratoire de Physicochimie Minérale associé au C.N.R.S., No. 116, I.N.S.A., 20, avenue Albert Einstein, 69621 Villeurbanne Cedex France |
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| Abstract: | From calorimetric measurements a model of solution is proposed for LiAlH4 in THF. It is ionised as LiAlH4 ? Li+ + AlH?4. For this reaction, ΔHi = 3.05 kcal mol?1 and the dissociation constant is K = 0.11. |
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