A convergent synthesis of octadeca-2E, 13Z-dienyl acetate, a pheromone component ofSynanthedon tipuliformis C. |
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Authors: | G Yu Ishmuratov M P Yakovleva R Ya Kharisov G I Kunafina E V Gorobets A V Kuchin G A Tolstikov |
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Institution: | (1) Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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Abstract: | A convergent synthesis of octadeca-2E, 13Z-dienyl acetate, a pheromone component ofSynanthedon tipuliformis C., has been developed. The synthesis is based on cross-coupling of 8-iodooct-2E-en-I-ol THP ether with dec-5Z-enyl bromide catalyzed by CuBr.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1529–1531, August, 1997. |
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Keywords: | dec-5Z-enyl bromide 8-iodo-1-(2-tetrahydropyranyloxy)oct-2E-ene crosscoupling octadeca-2E 13Z-dienyl acetate pheromone |
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