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A convergent synthesis of octadeca-2E, 13Z-dienyl acetate, a pheromone component ofSynanthedon tipuliformis C.
Authors:G Yu Ishmuratov  M P Yakovleva  R Ya Kharisov  G I Kunafina  E V Gorobets  A V Kuchin  G A Tolstikov
Institution:(1) Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation
Abstract:A convergent synthesis of octadeca-2E, 13Z-dienyl acetate, a pheromone component ofSynanthedon tipuliformis C., has been developed. The synthesis is based on cross-coupling of 8-iodooct-2E-en-I-ol THP ether with dec-5Z-enyl bromide catalyzed by CuBr. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1529–1531, August, 1997.
Keywords:dec-5Z-enyl bromide  8-iodo-1-(2-tetrahydropyranyloxy)oct-2E-ene  crosscoupling  octadeca-2E  13Z-dienyl acetate  pheromone
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