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| NH2自由基(~A)2A1,(~X)2B1电子态弯曲振动能级的理论计算 | |
| 引用本文： | 凤尔银,崔执凤,赵献章,陈东. NH2自由基(~A)2A1,(~X)2B1电子态弯曲振动能级的理论计算[J]. 原子与分子物理学报, 1999, 16(3) |
| 作者姓名： | 凤尔银 崔执凤 赵献章 陈东 |
| 作者单位： | 安徽师范大学物理系光谱与材料研究室,241000 |
| 基金项目： | 安徽省普通高校自然科学基金 |
| 摘 要： | 采用大振幅弯曲振动哈密顿，考虑到电子轨道角动量的ＲｅｎｎｅｒＴｅｌｅｒ效应，从理论上计算了自由基ＮＨ２Ａ２Ａ１，Ｘ２Ｂ１电子态弯曲振动及其Ｋ型转动能级，计算结果在较大的能量范围内与实验数据符合较好。 |
| 关 键 词： | Renner-Teller效应；大振幅弯曲振动 |
The theoretical calculation for the bending vibrational levels of the 2A1,2B1 states of NH2 radical |
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| FENG Er-yin,CUI Zhi-feng,ZHAO Xian-zhang,CHEN Dong. The theoretical calculation for the bending vibrational levels of the 2A1,2B1 states of NH2 radical[J]. Journal of Atomic and Molecular Physics, 1999, 16(3) | |
| Authors: | FENG Er-yin CUI Zhi-feng ZHAO Xian-zhang CHEN Dong |
| Abstract: | Based on the large amplitude bending vibrational Hamltonian and the Renner Teller effect describing vibronic interaction, the theoretical calculation for the bending vibrational and K type rotational levels of the 2A 1, 2B 1 states of NH 2 radical has been carried out. Our theoretical results are in good agreement with the experiment in broad energy range. |
| Keywords: | Renner Teller effect Large amplitude bending vibration |
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