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(p, ρ, T) properties, and apparent molar volumes V? of ZnBr2 in methanol at T = (298.15 to 398.15) K and pressures up to p = 40 MPa
Authors:E.C. Ihmels  J. Safarov  E. Hassel  J. Gmehling
Affiliation:a Laboratory for Thermophysical Properties LTP GmbH, Institute at the University of Oldenburg, D-26111 Oldenburg, Germany
b Department of Heat and Refrigeration Techniques, Azerbaijan Technical University, H. Javid Avn. 25, AZ1073 Baku, Azerbaijan
c Lehrstuhl fur Technische Thermodynamik, Fakultät Maschinenbau und Schiffstechnik, Universitat Rostock, Albert-Einstein-Str. 2, 18059 Rostock, Germany
d Department of Industrial Chemistry, University of Oldenburg, 26111 Oldenburg, Germany
Abstract:The (p, ρ, T) properties of pure methanol, the (p, ρ, T) properties and apparent molar volumes V? of ZnBr2 in methanol at T = (298.15 to 398.15) K and pressures up to p = 40 MPa are reported, and apparent molar volumes have been evaluated. The experimental (p, ρ, T, m) values were described by an equation of state. For the solutions the experiments were carried out at molalities m = (0.05772, 0.37852, 0.71585 and 1.95061) mol · kg−1 of zinc bromide.
Keywords:Absorption refrigeration machine   Vibration tube densimeter   Methanol     ZnBr2 solution   Equation of state   Apparent molar volume
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