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Effect of spin-orbit coupling in para-dihalogenobenzenes on the environment-induced frequency changes in their S1 ← S0 spectra |
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| Authors: | IA Ar&#x;ev GG Dyadyusha GV Klimusheva GM Soroka |
| Institution: | Institute of Colloid and Water Chemistry, Academy of Sciences of the Ukraine, Kiev, USSR;Institute of Organic Chemistry, Academy of Sciences of the Ukraine, Kiev, USSR;Institute of Physics, Academy of Sciences of the Ukraine, Kiev, USSR |
| Abstract: | The consequences of spin-orbit coupling in p-dihalogenobenzenes for solvent-induced shifts or S1 ← S0 spectral transitions, and for changes of S1-state vibrational frequencies compared with the S0 state, are assigned to mixing low-energy triplet states into the singlet-state system. |
| Keywords: | Present address: Institute of Physical and Chemical Research Wako-shi Saitama 351 Japan |
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