| Eu3+、Tb3+与1-乙酰乙酰吲哚、1,10-邻菲啰啉二元、三元体系在溶液中荧光光谱研究 |
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| 引用本文： | 吴玉銮,杨燕生.Eu3+、Tb3+与1-乙酰乙酰吲哚、1,10-邻菲啰啉二元、三元体系在溶液中荧光光谱研究[J].发光学报,1994,15(2):141-148. |
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| 作者姓名： | 吴玉銮 杨燕生 |
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| 作者单位： | 中山大学化学系, 广州 510275 |
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| 摘 要： | 观察了以不同比例溶解在乙醇中的Eu3+、Tb3+、1-乙酰乙酰吲哚(HL)和1,10-邻菲啉(Phen)的荧光光谱.结果表明HL能有效地把吸收的能量传递给Tb3+,而不能有效地传递给Eu3+.讨论了HL和Phen对Eu3+、Tb3+的配位作用及其对Eu3+或Tb3+所组成的三元体系中敏化发光性能的影响.
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| 关 键 词： | 荧光光谱 铕 铽 1-乙酰乙酰吲哚 1 10-邻菲啰啉 |
| 收稿时间： | 1993-09-08 |
STUDY ON FLUORESCENCE SPECTROSCOPY OF EUROPIUM AND TERBIUM COMPLEXED WITH l-ACETYLACETOINDOLE AND 1, 10-PHENANTHROLINE IN ETHANOL SOLUTION |
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| Wu Yuluan,Yang Yansheng.STUDY ON FLUORESCENCE SPECTROSCOPY OF EUROPIUM AND TERBIUM COMPLEXED WITH l-ACETYLACETOINDOLE AND 1, 10-PHENANTHROLINE IN ETHANOL SOLUTION[J].Chinese Journal of Luminescence,1994,15(2):141-148. |
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| Authors: | Wu Yuluan Yang Yansheng |
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| Institution: | Department of Chemistry, Zhongshan Uniursity, Guangzhou 510275 |
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| Abstract: | The fluorescence of Eu3+ and Tb3+ ions complexed with l-acetylacetoindole (HL) and l, 10-phenanthroline(Phen) in ethanol solution was investigated. It was found that there is a different influence for the addition of HL into the Eu3+-Phen and Tb3+-Phen systems respectively. This difference is discussed according to the ability of sensitization of HL for the luminescence of Eu3+ and Tb3+ respectively and also the coordination property of HL and Phen with Eu3+ and Tb3+. |
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| Keywords: | fluorescence spectra europium terbium 1-acetylacetoindole 1 10-phenanthroline |
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