New titanium and zirconium complexes with M-NH2 bonds formed by facile deprotonation of H3N.B(C6F5)3 |
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| Authors: | Mountford Andrew J Clegg William Harrington Ross W Humphrey Simon M Lancaster Simon J |
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| Affiliation: | Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK NR4 7TJ. |
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| Abstract: | ![]()
Facile deprotonation of H3N.B(C6F5)3 with [M(NMe2)4](M = Zr or Ti) yields the novel amidoborate complexes [Zr(NMe2)3{NH2B(C6F5)3}(HNMe2)] and [Ti(NMe2)3{NH2B(C6F5)3}]. |
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