Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines |
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| Authors: | Kondoh Azusa Yorimitsu Hideki Oshima Koichiro |
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| Institution: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto Daigaku Katsura, Kyoto, Japan. |
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| Abstract: | structure: see text]. Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene. |
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