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| 一个新颖的单齿桥联羧基——金属二聚物为顶点的发光分子矩形网格(英) | |
| 引用本文： | 袁荣鑫,张 静,熊仁根,范洪筠.一个新颖的单齿桥联羧基——金属二聚物为顶点的发光分子矩形网格(英)[J].无机化学学报,2004,20(6):632-634. |
| 作者姓名： | 袁荣鑫 张 静 熊仁根 范洪筠 |
| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093;常熟理工学院化学科学与技术系,常熟,215500 2. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 3. 3X-ray Crystallography Unit,School of physics,Universiti Sains Malaysia,11800,USM,Penang,Malaysia |
| 基金项目： | 国家重点基础研究发展规划资助项目(No.G2000077500)，国家自然科学基金资助项目 |
| 摘 要： | The hydrothermal reaction of 4-pyridylacrylic acid (4-HPYA) with Cu(MeCN)4](BF4) and PPh3 gives rise to an unprecedented luminescent molecular square grid, Cu(Ⅰ)(4-PYA)(PPh3)]n (1) which may be used as a sensor. CCDC: 236419. |
| 关 键 词： | 水热合成 发光 分子矩形网格 一价铜配合物 |
An Unprecedented Luminescent Molecular Square Grid Based on Monodentate Bridging Carboxylate-Metal Dimer as Corner Unit |
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| YUAN Rong-Xin,ZHANG Jing,XIONG Ren-Gen and FUN Hoong-Kun.An Unprecedented Luminescent Molecular Square Grid Based on Monodentate Bridging Carboxylate-Metal Dimer as Corner Unit[J].Chinese Journal of Inorganic Chemistry,2004,20(6):632-634. | |
| Authors: | YUAN Rong-Xin ZHANG Jing XIONG Ren-Gen and FUN Hoong-Kun |
| Institution: | Coordination Chemistry Institute, the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;Department of Chemistry, Chgangshu Institute of Technology, Changshu 215500,Coordination Chemistry Institute, the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800, USM, Penang, Malaysia |
| Abstract: | The hydrothermal reaction of 4-pyridylacrylic acid (4-HPYA) with Cu(MeCN)4](BF4) and PPh3 gives rise to an unprecedented luminescent molecular square grid, Cu(Ⅰ)(4-PYA)(PPh3)]n (1) which may be used as a sensor. |
| Keywords: | hydrothermal synthesis luminescence molecular square grid copper(I) complex |
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