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Synthesis of (-)-chaetominine |
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| Authors: | Snider Barry B Wu Xiaoxing |
| Affiliation: | Department of Chemistry MS 015, Brandeis University, Waltham, MA 02454-9110, USA. snider@brandeis.edu |
| Abstract: | The tricyclic hydroxy imidazolidinone was converted to chaetominine in seven steps in 22% overall yield. The key step was the construction of the delta-lactam by heating an amino ester with a catalytic amount of DMAP in toluene at reflux. |
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