Measurement of circular dichroism spectra of liquid/liquid interface by centrifugal liquid membrane method. |
| |
| Authors: | Sayaka Wada Kazuhiko Fujiwara Hideaki Monjushiro Hitoshi Watarai |
| |
| Affiliation: | Department of Chemistry, Graduate School of Science, Osaka University, 1-1, Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan. |
| |
| Abstract: | The direct measurement of the circular dichroism (CD) spectra of liquid/liquid interface has been achieved for the first time by the centrifugal liquid membrane (CLM) method combined with a conventional CD spectropolarimetry. In the sample chamber of the CD spectropolarimeter, a cylindrical glass cell containing small amounts of organic and aqueous phases was rotated at ca. 7000 rpm to generate a two-phase liquid membrane with a high specific interfacial area. The CD spectra of the J-aggregate of protonated 5,10,15,20-tetraphenylporphyrin formed at the toluene/sulfuric acid interface in the rotating cell have been measured. The results demonstrated the novelty and advantages of this method. |
| |
| Keywords: | |
|
|
