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Strong two-photon absorption of self-assembled butadiyne-linked bisporphyrin
Authors:Ogawa Kazuya  Ohashi Atsushi  Kobuke Yoshiaki  Kamada Kenji  Ohta Koji
Affiliation:Graduate School of Materials Science, Nara Institute of Science and Technology, Japan.
Abstract:Two-photon absorption (2PA) properties of self-assembled porphyrins were investigated. The butadiyne-linked porphyrin array exhibited a 20 times larger 2PA cross section than the meso-meso-linked self-assembled array due to the expansion of pi-conjugation. Higher-order nonlinear absorption was also observed in the former porphyrin.
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