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A New Heated Nickel Oxyhydroxide Covered Nickel Wire Electrode and Its Improved Electrocatalytic Oxidation for Methanol
Authors:Shao‐Hua Wu  Bao‐Jian Zhu  Zong‐Xiong Huang  Jian‐Jun Sun
Institution:Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, P.?R. China tel/fax: +86?591?22866136
Abstract:A new heated nickel oxyhydroxide covered nickel wire electrode (HNONE) was fabricated and AC heating circuit was used to heat the electrode. Furthermore, the improved electrocatalytic activity of the HNONE for methanol oxidation at elevated electrode temperature was demonstrated. A detection limit of 2.1×10?4 M (S/N=3) could be obtained with an electrode temperature of 80 °C, about one magnitude lower than that at room temperature 20°. And the sensitivity was also enhanced about 10 times.
Keywords:Heated nickel oxyhydroxide covered nickel wire electrode  Electrocatalytic oxidation  Methanol
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