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Synthesis and Study of Plasmon‐Induced Carrier Behavior at Ag/TiO2 Nanowires
Authors:Dr. Haiyan Li  Wenbo Lu  Jingqi Tian  Yonglan Luo  Prof. Abdullah M. Asiri  Abdulrahman O. Al‐Youbi  Prof. Xuping Sun
Affiliation:1. State Key Lab of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (P.R. China), Fax: (+86)?431‐85262065;2. Graduate School of the Chinese Academy of Sciences, Beijing 100039 (P.R. China);3. Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia);4. Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah 21589 (Saudi Arabia)
Abstract:
Nanocomposites of Ag/TiO2 nanowires with enhanced photoelectrochemical performance have been prepared by a facile solvothermal synthesis of TiO2 nanowires and subsequent photoreduction of Ag+ ions to Ag nanoparticles (AgNPs) on the TiO2 nanowires. The as‐prepared nanocomposites exhibited significantly improved cathodic photocurrent responses under visible‐light illumination, which is attributed to the local electric field enhancement of plasmon resonance effect near the TiO2 surface rather than by the direct transfer of charge between the two materials. The visible‐light‐driven photocatalytic performance of these nanocomposites in the degradation of methylene blue dye was also studied, and the observed improvement in photocatalytic activity is associated with the extended light absorption range and efficient charge separation due to surface plasmon resonance effect of AgNPs.
Keywords:nanoparticles  photocatalysis  photoreduction  silver  surface plasmon resonance  titanium
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