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Water‐Promoted Kinetic Separation of trans‐ and cis‐Limonene Oxides
Authors:Zhao‐Bing Xu  Jin Qu
Affiliation:State Key Laboratory of Elemento‐Organic Chemistry, Nankai University, Tianjin 300071, China
Abstract:
The efficient hydrolytic kinetic separation of trans/cis‐(R)‐(+)‐limonene oxides was realized in a 1:1 mixed solvent of water and 1,4‐dioxane without additional catalyst. Optically pure trans‐(R)‐(+)‐limonene oxide was recovered in high yield (77%).
Keywords:trans/cis‐(R)‐(+)‐limonene oxides  kinetic separation  water  1,4‐dioxane
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