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Opposing Influences of Ruffling and Doming Deformation on the 4‐N Cavity Size of Porphyrin Macrocycles: The Role of Heme Deformations Revealed |
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| Authors: | Dr. Zaichun Zhou Min Shen Prof. Chenzhong Cao Qiuhua Liu Ziqiang Yan |
| Affiliation: | School of Chemistry and Chemical Engineering, Key Laboratory of Theoretical Chemistry, and Molecular Simulation of Ministry of Education, Hunan University of Science and Technology, Taoyuan Road, Xiangtan, 411201(P.R. China), Fax: (+)?86‐731‐58290509 |
| Abstract: | |
| Keywords: | biomimetic synthesis heme proteins macrocycles metalloenzymes porphyrinoids |