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A novel synthetic route for LiFePO_4/C cathode materials by addition of starch for lithium-ion batteries
引用本文:Shao Hua Luo,Zi Long Tang,Jun Biao Lu,Zhong Tai Zhang State Key Laboratory of New Ceramics and Fine Processing,Department of Materials Science and Engineering,Tsinghua University,Beijing 100084,China Graduate School at Shenzhen,Tsinghua University,Shenzhen 518055,China. A novel synthetic route for LiFePO_4/C cathode materials by addition of starch for lithium-ion batteries[J]. 中国化学快报, 2007, 18(2): 237-240. DOI: 10.1016/j.cclet.2006.12.041
作者姓名:Shao Hua Luo  Zi Long Tang  Jun Biao Lu  Zhong Tai Zhang State Key Laboratory of New Ceramics and Fine Processing  Department of Materials Science and Engineering  Tsinghua University  Beijing 100084  China Graduate School at Shenzhen  Tsinghua University  Shenzhen 518055  China
作者单位:Shao Hua Luo,Zi Long Tang,Jun Biao Lu,Zhong Tai Zhang State Key Laboratory of New Ceramics and Fine Processing,Department of Materials Science and Engineering,Tsinghua University,Beijing 100084,China Graduate School at Shenzhen,Tsinghua University,Shenzhen 518055,China
基金项目:国家自然科学基金;清华大学校科研和教改项目
摘    要:LiFePO4/Carbon composite cathode material was prepared using starch as carbon source by spray-pelleting and subsequent pyrolysis in N2. The samples were characterized by XRD, SEM, Raman, and their electrochemical performance was investigated in terms of cycling behavior. There has a special micro-morphology via the process, which is favorable to electrochemical properties. The discharge capacity of the LiFePO4.C composite was 170 mAh g-1, equal to the theoretical specific capacity at 0.1 C rate. At 4 C current density, the specific capacity was about 80 mAh g-1, which can satisfy for transportation applications if having a more flat discharge flat.

收稿时间:2006-10-10

A novel synthetic route for LiFePO4/C cathode materials by addition of starch for lithium-ion batteries
Shao Hua Luo,Zi Long Tang,Jun Biao Lu,Zhong Tai Zhang. A novel synthetic route for LiFePO4/C cathode materials by addition of starch for lithium-ion batteries[J]. Chinese Chemical Letters, 2007, 18(2): 237-240. DOI: 10.1016/j.cclet.2006.12.041
Authors:Shao Hua Luo  Zi Long Tang  Jun Biao Lu  Zhong Tai Zhang
Affiliation:1. State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China;2. Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China
Abstract:LiFePO4/Carbon composite cathode material was prepared using starch as carbon source by spray-pelleting and subsequent pyrolysis in N2. The samples were characterized by XRD, SEM, Raman, and their electrochemical performance was investigated in terms of cycling behavior. There has a special micro-morphology via the process, which is favorable to electrochemical properties. The discharge capacity of the LiFePO4.C composite was 170 mAh g-1, equal to the theoretical specific capacity at 0.1 C rate. At 4 C current density, the specific capacity was about 80 mAh g-1, which can satisfy for transportation applications if having a more flat discharge flat.
Keywords:Lithium-ion batteries  Cathode material  Carbon coated LiFePO4  Spray-pelleting
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