| Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide |
| |
| 引用本文： | Fandong Meng,Genhui Xu,Baowei Wang,Xinbin Ma1. School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China 2. Luoyang Petrochemical Engineering Corporation,Luoyang 471003,China[Manuscript received March 13,2002, revised Apr. Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide[J]. 天然气化学杂志, 2002, 0(Z1) |
| |
| 作者姓名： | Fandong Meng Genhui Xu Baowei Wang Xinbin Ma1. School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China 2. Luoyang Petrochemical Engineering Corporation Luoyang 471003 China[Manuscript received March 13 2002 revised Apr |
| |
| 摘 要： | This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation.
|
Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide |
| |
| Fandong Meng,Genhui Xu,Baowei Wang,Xinbin Ma. School of Chemical Engineering and Technology,Tianjin University,Tianjin ,China . Luoyang Petrochemical Engineering Corporation,Luoyang ,China[Manuscript received March ,, revised Apr. Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide[J]. Journal of Natural Gas Chemistry, 2002, 0(Z1) |
| |
| Authors: | Fandong Meng Genhui Xu Baowei Wang Xinbin Ma. School of Chemical Engineering Technology Tianjin University Tianjin China . Luoyang Petrochemical Engineering Corporation Luoyang China[Manuscript received March revised Apr |
| |
| Abstract: | This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation. |
| |
| Keywords: | CO coupling diethyl oxalate kinetics and mechanism simulation scale-up test |
| 本文献已被 CNKI 等数据库收录！ |
