Titanocene(III)-catalyzed formation of indolines and azaindolines |
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| Authors: | Wipf Peter Maciejewski John P |
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| Institution: | Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA. pwipf@pitt.edu |
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| Abstract: | Reductive cyclization of epoxides tethered to substituted anilines and aminopyridines in the presence of 3 mol % of titanocene dichloride and stoichiometric manganese metal promotes a radical annulation to form 3,3-disubstituted indolines and azaindolines. |
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