| A New Diiminopyridyl Cobalt Complex [CoCl_2L]（L=2,6-Bis（N,N＇-bis（2,6-diisopropyl-4-（2,3-dimethyoxylbenzoylamide）phenylimino））pyridine） |
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| 作者姓名： | LONG Ze-Rong ZHAO Qi-Long LI Shao-Guang XIA Ya-Na WU Biao |
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| 作者单位： | [1]State Key Laboratory for Oxo Synthesis ＆ Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China [2]Graduate School of Chinese Academy of Sciences, Beijing 100049, China |
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| 基金项目： | Supported by the ＂Bairen Jihua＂ project of Chinese Academy of Sciences |
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| 摘 要： | The reaction of CoCl2·6H2O with 2,6-bis(N,N'-bis(2,6-diisopropyl-4-(2,3-dimethy-oxyl-benzoylamide)phenylimino))pyridine(L) afforded the complex CoCl2L],which was fully characterized by elemental analysis,UV-vis,IR spectroscopy,fluorescence,and X-ray diffraction analysis.The compound is of triclinic system,space group P1 with a = 13.058(3),b = 13.798(3),c = 16.695(3) ,α = 98.191(3),β = 102.792(3),γ = 101.820(3)°,V = 2815.0(9) 3,Z = 2,F(000) = 1122,μ = 0.45 mm-1,R = 0.061 and wR = 0.1349 for 9842 observed reflections(Ⅰ 2σ(Ⅰ)).The Co(Ⅱ) center adopts a distorted square-pyramidal coordination geometry.The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.
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| 关 键 词： | 二异丙基 吡啶 紫外可见分光光度计 π-π堆积作用 射线衍射分析 有机化合物 金字塔结构 二甲氧基 |
A New Diiminopyridyl Cobalt Complex [CoCl_2L]（L=2,6-Bis（N,N＇-bis（2,6-diisopropyl-4-（2,3-dimethyoxylbenzoylamide）phenylimino））pyridine） |
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| LONG Ze-Rong,ZHAO Qi-Long,LI Shao-Guang,XIA Ya-Na,WU Biao.A New Diiminopyridyl Cobalt Complex [CoCl_2L]（L=2,6-Bis（N,N＇-bis（2,6-diisopropyl-4-（2,3-dimethyoxylbenzoylamide）phenylimino））pyridine）[J].Chinese Journal of Structural Chemistry,2010(6):869-874. |
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| Abstract: | The reaction of CoCl2·6H2O with 2,6-bis(N,N'-bis(2,6-diisopropyl-4-(2,3-dimethy-oxyl-benzoylamide)phenylimino))pyridine(L) afforded the complex CoCl2L],which was fully characterized by elemental analysis,UV-vis,IR spectroscopy,fluorescence,and X-ray diffraction analysis.The compound is of triclinic system,space group P1 with a = 13.058(3),b = 13.798(3),c = 16.695(3) ,α = 98.191(3),β = 102.792(3),γ = 101.820(3)°,V = 2815.0(9) 3,Z = 2,F(000) = 1122,μ = 0.45 mm-1,R = 0.061 and wR = 0.1349 for 9842 observed reflections(Ⅰ > 2σ(Ⅰ)).The Co(Ⅱ) center adopts a distorted square-pyramidal coordination geometry.The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions. |
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| Keywords: | 2 6-bis（N N＇-bis（2 6-diisopropyl-4-（2 3-dimethyoxylbenzoylamide）phenylimino）） pyridine cobalt crystal structure fluorescence |
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