| A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units |
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| 引用本文： | JingLinCHEN LiYiZHANG ZhongNingCHEN. A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units[J]. 中国化学快报, 2005, 16(3): 372-374 |
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| 作者姓名： | JingLinCHEN LiYiZHANG ZhongNingCHEN |
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| 作者单位： | [1]StateKeyLaboratoryofStructuralChemistry,FujianInstituteofResearchontheStructureofMatter,TheChineseAcademyofSciences,Fuzhou350002／／GraduateSchooloftheChineseAcademyofSciences,Beijing100039 [2]StateKeyLaboratoryofStructuralChemistryFujianInstituteofResearchontheStructureofMatter,TheChineseAcademyofSciences,Fuzhou350002 |
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| 摘 要： | ![]()
A novel dimeric complex [Ru3^111,111,11(μ3-O)(μ-CH3COO)(CO)]2(μ-dppf)(μ-odppf) (dppf=1, 1‘-bis(diphenylphosphio)ferrocene, odppf = 1, 1‘-bis(oxodiphenylphosphoranyl)ferrocene) (1) of oxo-centered triruthenium-aectate cluster units was synthesized and characterized by X-ray crystallography. Compound 1 exhibits a cyclic structure formed by linkages of two triruthenium cluster units Ru3^111,111,11(μ3-O)(μ-CH3COO)6(CO) through dppf and odppf ligands, respectively. The diameter of the molecular loop is ca. 1.0 rim.
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| 关 键 词： | 八核金属串配合物 羧酸酯 晶体结构 二膦 三钌配合物 合成 光谱分析 |
A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units |
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| Jing Lin CHEN,,Li Yi ZHANG,Zhong Ning CHEN State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou Graduate School of the Chinese Academy of Sciences,Beijing. A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units[J]. Chinese Chemical Letters, 2005, 16(3): 372-374 |
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| Authors: | Jing Lin CHEN Li Yi ZHANG Zhong Ning CHEN State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Graduate School of the Chinese Academy of Sciences Beijing |
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| Affiliation: | Jing Lin CHEN1,2,Li Yi ZHANG1,Zhong Ning CHEN1* 1State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou 350002 2Graduate School of the Chinese Academy of Sciences,Beijing 100039 |
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| Abstract: | ![]()
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| Keywords: | Carboxylate crystal structure diphosphine ruthenium cluster complex. |
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