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Preparation of activated carbon from cotton stalk and its application in supercapacitor
Authors:Mingde Chen  Xueya Kang  Tuerdi Wumaier  Junqing Dou  Bo Gao  Ying Han  Guoqing Xu  Zhiqiang Liu  Lu Zhang
Institution:1. Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi, Xinjiang, 830011, China
2. Graduate University of Chinese Academy of Sciences, Beijing, 100049, China
Abstract:High specific capacitance and low cost are the critical requirements for a practical supercapacitor. In this paper, a new activated carbon with high specific capacitance and low cost was prepared, employing cotton stalk as the raw material, by using the phosphoric acid (H3PO4) chemical activation method. The optimized conditions were as follows: the cotton stalk and activating agent with a mass ratio of 1:4 at an activation temperature of 800 °C for 2 h. The samples were characterized by nitrogen adsorption isotherms at 77 K. The specific surface area and pore volume of activated carbon were calculated by Brunauer–Emmett–Teller (BET) and t-plot methods. With these experimental conditions, an activated carbon with a BET surface area of 1,481 cm2?g?1 and micropore volume of 0.0377 cm3?g?1 was obtained. The capacitance of the prepared activated carbon was as high as 114 F?g?1.The results indicate that cotton stalk can produce activated carbon electrode materials with low cost and high performance for electric double-layer capacitor.
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