Electrocrystallization of Molybdenum Carbide in Oxide Melts and the Influence of Electrolysis Parameters on Grain Size and Quality of Deposits |
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| Authors: | Malyshev V V Kushkhov Kh B Shapoval V I |
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| Institution: | (1) Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine;(2) Kabardino-Balkar State University, Nalchik, Kabardino-Balkariya, Russia |
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| Abstract: | The influence of current density and temperature on crystal grain size in electroplating of molybdenum carbide from tungstate-molybdate-carbonate melts was studied. The initial stages of molybdenum carbide electrocrystallization from tungstate-molybdate-carbonate melts at 750-900° on different substrates were studied by the method of galvanostatic switch-on curves and in situ microstructural analysis. |
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