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Chemical treatments on the cuticle layer enhancing the uranium(VI) uptake from aqueous solution by amidoximated wool fibers
Authors:Zhang  Fan  Chen  Min  Hu  Sheng  Cheng  Haiming
Affiliation:1.National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu, 610065, Sichuan, China
;2.Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang, 621900, Sichuan, China
;
Abstract:

Urea, sodium hydroxide and sodium sulfide were used to treat the cuticle layer of wool before graft copolymerization and amidoximation to enhance the uranium uptaking capacity of amidoximated wool fiber based adsorbent (Wool-g-AOs). The wool-g-AOs were used for recovery of U(VI) from aqueous solutions. The simulated nuclear industry effluent was used for investigating the selectivity and industrial applicability of Wool-g-AOs. The adsorption of uranium(VI) on Wool-g-AOs was pH dependent. The Langmuir model fitted well with the equilibrium data. Kinetic data were fitted well to pseudo second order model.

Keywords:
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