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A Novel Approach for the Surface Modification of Polymeric Membrane with Phospholipid Polymer
引用本文:QingWenDAI ZhiKangXU JianWU. A Novel Approach for the Surface Modification of Polymeric Membrane with Phospholipid Polymer[J]. 中国化学快报, 2004, 15(8): 993-996
作者姓名:QingWenDAI ZhiKangXU JianWU
作者单位:[1]InstituteofPolymerScience,ZhejiangUniversity,Hangzhou310027 [2]DepartmentofChemistry,ZhejiangUniversity,Hangzhou310027
摘    要:
A new economic and convenient method to modify the surface of microporous polypropylene (PP) membranes with phospholipid polymer was given. The process included the photo-irradiated graft polymerization of N,N-dimethylaminoethyl methacrylate (DMAEMA) and the ring-opening reaction of the grafted polyDMAEMA with 2-alkyloxy-2-oxide-1,3,2-dioxo-phospholanes (AOP). Four AOPs, whose alkyloxy groups consisted of dodecyl, tetradecyl,hexadecyl and octadecyl moieties, were used to convert the grafted polyDMAEMA to phospholipidpolymers. FT-IR spectra confirmed the chemical change of membrane surface. Platelets adhesion experiment indicated that PP membrane with excellent blood compatible surface could be fabricated by this method.

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A Novel Approach for the Surface Modification of Polymeric Membrane with Phospholipid Polymer
Qing Wen DAI,Zhi Kang XU,Jian WUinstitute of Polymer Science,Zhejiang University,Hangzhou. A Novel Approach for the Surface Modification of Polymeric Membrane with Phospholipid Polymer[J]. Chinese Chemical Letters, 2004, 15(8): 993-996
Authors:Qing Wen DAI  Zhi Kang XU  Jian WUinstitute of Polymer Science  Zhejiang University  Hangzhou
Affiliation:Qing Wen DAI,Zhi Kang XU,Jian WUinstitute of Polymer Science,Zhejiang University,Hangzhou 310027 Department of Chemistry,Zhejiang University,Hangzhou 310027
Abstract:
A new economic and convenient method to modify the surface of microporous polypropylene (PP) membranes with phospholipid polymer was given. The process included the photo-irradiated graft polymerization of N,N-dimethylaminoethyl methacrylate (DMAEMA) and the ring-opening reaction of the grafted polyDMAEMA with 2-alkyloxy-2-oxide-1,3,2-dioxo-phospholanes (AOP). Four AOPs, whose alkyloxy groups consisted of dodecyl, tetradecyl, hexadecyl and octadecyl moieties, were used to convert the grafted polyDMAEMA to phospholipid polymers. FT-IR spectra confirmed the chemical change of membrane surface. Platelets adhesion experiment indicated that PP membrane with excellent blood compatible surface could be fabricated by this method.
Keywords:Surface modification   phospholipid polymer   platelets adhesion.
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