Equilibrium NH-acidity of 1,4-dihydropyridines and 4,5-dihydroindeno[1,2-b]pyridines |
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Authors: | B A Vigante M I Terekhova Ya Ya Ozols E S Petrov G Ya Dubur |
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Institution: | (1) Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006 Riga;(2) L. Ya. Karpov Scientific Research Physicochemical Institute, 107120 Moscow |
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Abstract: | The patterns governing the dependence of NH-acidity on the presence of -, - and -substituents in the 1,4-dihydropyridine ring and on their nature have been established by comparison of the pKa values of monocyclic 1,4-dihydropyridines and 4,5-dihydroindenopyridines. Additional data were obtained on the influence of the the electronic effects of sulfur-containing substitutents on the reaction center in the dihydropyridine molecules.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1228–1231, September, 1989. |
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