Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti(III)/Ti(IV) |
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| Authors: | Chippindale Ann M Grimshaw Mark R Powell Anthony V Cowley Andrew R |
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| Affiliation: | School of Chemistry, The University of Reading, Whiteknights, Reading, Berks RG6 6AD, UK. a.m.chippindale@rdg.ac.uk |
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| Abstract: | The first 3-D open-framework TiGaPO complex, constructed from Ti(III)O(6), Ti(IV)O(6), GaO(4), and PO(4) polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure. |
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