Recent advances in the application of the Oppolzer camphorsultam as a chiral auxiliary |
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| Institution: | 1. Department of Organic Chemistry, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50 370 Wrocław, Poland;2. Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie St., 50 383 Wrocław, Poland;1. College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, People’s Republic of China;2. College of Science, Nanjing Forestry University, Nanjing 210037, People’s Republic of China;3. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore |
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| Abstract: | Oppolzer’s camphorsultam has attracted much attention as an efficient chiral auxiliary, and is one of the most powerful synthetic tools in asymmetric synthesis. The sultam chiral auxiliary can be applied in a variety of different reactions such as alkylations, allylations, 1,3-dipolar cycloadditions, cyclopropanation, reductions, Diels–Alder, aldol and ene reactions. These applications have been highly successful in the stereoselective construction of a number of important natural products via total synthesis. The present review is focused on the utility and versatility of the sultam in various asymmetric reactions. |
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