The first samarium(II)-mediated aryl radical cyclisation onto an aromatic ring |
| |
| Authors: | Ohno Hiroaki Iwasaki Hiroki Eguchi Toru Tanaka Tetsuaki |
| |
| Affiliation: | Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan. |
| |
| Abstract: | ![]()
Intramolecular arylation of aryl radicals was mediated by SmI(2)/HMPA in the presence of i-PrOH to give spirocycles and/or reduced cine-cyclised products, while the reaction in the absence of i-PrOH gave the rearomatised fused rings. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
