SYNTHESIS,IDENTIFICATION AND SURFACE ACTIVITY OF 2-AMINE-2-DEOXY-3-O-n-OCTYL-D-GLUCOPYRANOSE HYDROCHLORIDE |
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Authors: | J. M. Vega Pérez C. Gómez Herrera F. J. Ruiz Rodriguez M. B. Riego Martín |
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Affiliation: | 1. Departamento de Química Orgáinica , Facultad de Farmacia, Universidad de Sevilla , Spain;2. Instituto de la Grasa y sus Derivados (C.S.I.C.) , Sevilla, Spain |
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Abstract: | ![]() The synthesis and identification of this product are described. Variations of surface tension of its aqueous solutions versus concentration (ranged between 3 and 95 mmol/L) and temperature (ranged between 20.0 and 47.5°C) are studied. The isothermal plots of surface tension versus the logarithm of the concentration show a continous decrease, with a sharp change of slope at a concentration about 6.5 mmol/L, for all the studied temperatures. A second change of slope, less pronounced, appears for a higher concentration. This concentration value increases from 28 to 42 mmol/L when temperature is raised from 20.0 to 47.5°C. The changes of slope can be attributed mainly to micellization of neutral amine molecules resulting from hydrolysis of surface active cations, which present a weak electrolytic character. |
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