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Insect pheromones and their analogs. LX. Stereocontrolled synthesis of sex pheromones ofDrosophila mulleri andMayetiola destructor
Authors:R Ya Kharisov  N I Petukhova  A R Davletova  N M Ishmuratova  V V Zorin  G Yu Ishmuratov  G A Tolstikov
Institution:(1) Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, prospekt Oktyabrya 71, 450054 Ufa;(2) Ufa State Petroleum Technical University, ul. Kosmonavtov, 1, 450062 Ufa
Abstract:Syntheses are developed for 2S-tridecyl- and 2S-tridec-10E-enylacetates, sex pheromones of the fruit flyDrosophila mulleri and the Hessian flyMayetiola destructor, respectively, that are based on ethyl-3S-hydroxybutanoate, a product from enzymatic reduction of ethyl acetoacetate by the soil yeast strain ldquo80-1rdquo.Work performed under the auspices of the Federal program ldquoIntegratsiyardquo of the RF (Contract No. A 0005).Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 167–169, March–April, 2000.
Keywords:pheromones  Drosophila mulleri  Mayetiola destructor  ethyl-3S-hydroxybutanoate  2S-tridecylacetate  2S-tridec-10E-enylacetate  synthesis
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