| Study on Lead Dioxide Modified Electrode and Its Application in Detection of Phenols |
| |
| 引用本文： | 艾仕云,高梦南,蔡琪,孙郑冬,金利通. Study on Lead Dioxide Modified Electrode and Its Application in Detection of Phenols[J]. 中国化学, 2003, 21(2): 157-161. DOI: 10.1002/cjoc.20030210214 |
| |
| 作者姓名： | 艾仕云 高梦南 蔡琪 孙郑冬 金利通 |
| |
| 作者单位： | Department of Chemistry，East China Normal University，Shanghai 200062，China，Department of Chemistry，East China Normal University，Shanghai 200062，China，Department of Chemistry，East China Normal University，Shanghai 200062，China，Department of Chemistry，East China Normal University，Shanghai 200062，China，Department of Chemistry，East China Normal University，Shanghai 200062，China |
| |
| 基金项目： | ProjectsupportedbytheKeyTechnologyResearchandDevelopmentProgramofChina’sTenthFive YearPlan (No .2 0 0 1BA2 10A0 4) |
| |
| 摘 要： | IntroductionOflate,thereisagreatinterestintheimprovementofleaddioxideasananodematerialforelectrosynthesis,ozonegenerationandwastewatertreatmentowingtoitshighelectri calconductivity ,largeoxygenoverpotentialandchemicalin ertness.1 5PbO2 canbeobtainedasanodicdepositsfromsolu tionsofthelow valenceions,basicstudiesontheseelec trodesaremainlyconfinedtothenucleationgrowthprocessofleaddioxidecrystallites ,ormodifiedbyothercationsinordertoimproveitsproperties.6 However,itselectrocatalyticactivi tydepe…
|
| 关 键 词： | 二氧化铅 氧化物修饰电极 苯酚 分析 应用 |
Study on Lead Dioxide Modified Electrode and Its Application in Detection of Phenols |
| |
| Ai Shi‐Yun,Gao Meng‐Nan,Cai Qi,Sun Zheng‐Dong,Jem Li‐Tong. Study on Lead Dioxide Modified Electrode and Its Application in Detection of Phenols[J]. Chinese Journal of Chemistry, 2003, 21(2): 157-161. DOI: 10.1002/cjoc.20030210214 |
| |
| Authors: | Ai Shi‐Yun Gao Meng‐Nan Cai Qi Sun Zheng‐Dong Jem Li‐Tong |
| |
| Abstract: | The conditions for the preparation of PbO2 modified Pt rotation disc electrode in solutions containing HC104 and Pb(II) were studied, and the morphology and composition of the obtained PbO2 film were characterized by SEM and XRD techniques, respectively. The results show that the modification process of PbO is dependent on the rotation velocity of the electrode and the concentrations of HCIO4 and Pb(II). And it was observed that the obtained PbO2 film was rutile β‐PDO2 structure. At a certain positive potential, HO· and HO2· radicals can be generated on the surface of the modified PbO2/Pt electrode and then oxidize phenols. According to the change of the responding anodic current, the determination of phenols was realizable and good results were obtained. |
| |
| Keywords: | PbO 2 modified electrode phenol determination |
| 本文献已被 CNKI 等数据库收录！ |
