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Novel dihydrazone based polymers for electrophotography
Authors:V. Getautis  J.V. Grazulevicius  T. Malinauskas  J. Sidaravicius
Affiliation:a Faculty of Chemical Technology, Kaunas University of Technology, Radvilenu pl. 19, LT-50270 Kaunas, Lithuania
b Department of Solid State Electronics, Vilnius University, Sauletekio 9, LT-10222 Vilnius, Lithuania
c Department of Polygraphic Machines, Vilnius Gediminas Technical University, Vilnius, LT-10223, Lithuania
d Institute of Physics, Savanoriu 231, LT-02300 Vilnius, Lithuania
Abstract:
The novel family of hole-transporting polymers containing hydrazone moieties is reported. The polymers were prepared in polyaddition reaction of dihydrazone-containing diepoxides with bifunctional nucleophilic linking agents in the presence of catalyst triethylamine. Obtained polymers were found to constitute novel polymeric hole transporting materials characterized by differential scanning calorimetry and time of flight method. The highest hole drift mobility in the newly synthesized polymers exceed 10−5 cm2 V−1 s−1 at an electric field of 106 V cm−1.
Keywords:Polymers   Polyaddition   Hydrazones   Epoxides   Charge transport   Electrophotography
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