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Solubility and Flory Huggins parameters of SBES, poly(styrene-b-butene/ethylene-b-styrene) triblock copolymer, determined by intrinsic viscosity
Authors:G. Ovejero,P. Pé  rez,I. Guzmá  n
Affiliation:a Grupo de Catálisis y Procesos de Separación (CyPS), Departamento de Ingenier?´a Qu?´mica, Facultad de C. Qu?´micas, Universidad Complutense de Madrid Avda. Complutense s/n, 28040 Madrid, Spain
b Alfonso Cortina Technology Center, REPSOL-YPF, 28933 Móstoles, Madrid, Spain
Abstract:
Solubility parameter and Flory Huggins interaction parameter of a triblock SBES have been obtained from intrinsic viscosity measurements. The solubility of the block copolymer in all solvents (methyl-cyclohexane, cyclohexane, cyclopentane, toluene and benzene) was found good except in the case of n-hexane. The results obtained are similar to other found in literature for SBR and SBS rubbers, and indicate that cyclohexane and cyclopentane and methylcyclohexane are the most compatible solvents for this kind of polymer.
Keywords:Poly(styrene-b-butene/ethylene-b-styrene) triblock copolymers   Intrinsic viscosity   Solubility parameter   Flory Huggins parameter
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