Thermal behaviour of poly(allyl azide) |
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Authors: | Gaur B Lochab B Choudhary V Varma I K |
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Institution: | (1) Centre for Polymer Science and Engineering, Indian Institute of Technology Delhi, Hauz Khas, New-Delhi, 110016, India |
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Abstract: | The paper describes the synthesis of low molecular mass poly(allyl chloride) (PAC) (M
n= 856-3834 g mol-1) using Lewis acid (ALCL3, FeCL3, TiCL4) and al powder. Branching in PAC was indicated on the basis of elemental analysis and 1H-NMR spectroscopy. azidation of pac could be carried out at 100°C by using NaN3 and DMSO as solvent. Curing of poly(allyl azide) (PAA) by cyclic dipolar addition reaction with EGDMA (ethylene glycol dimethacrylate,
5-45 phr) was investigated by differential scanning calorimetry and structure of cured polymer was confirmed by FTIR. A two-step
mass loss was exhibited by uncured and cured PAA in nitrogen atmosphere. A mass loss of 20-28% (155-274°C) and 50-61% (330-550°C)
was observed.
This revised version was published online in July 2006 with corrections to the Cover Date. |
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Keywords: | dipolarophiles poly(allyl azide) poly(allyl chloride) thermal behaviour curing studies triazole |
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