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The study on the dynamic response performance of PEMFC with electrodeposited RuO_2·xH_2O-Pt/C electrode
作者单位:Department of Environment & Chemical Engineering,Dalian Jiaotong University,Dalian 116028,Liaoning,China
基金项目:supported by the National Natural Science Foundation of China (No.20776023, No.20976018)
摘    要:
Dynamic response performance of proton exchange membrane (PEM) fuel cells affects its durability and reliability significantly. In this study, electrodeposited RuO2 xH2O-Pt/C was prepared to promote the PEM fuel cell dynamic response performance. The prepared RuO2 xH2O-Pt/C was characterized by scanning electron microscopy (SEM) equipped with energy disperse spectroscopy (EDS), which shows that RuO2 xH2O was electrodeposited on the surface of Pt/C. Performance of single cells with and without RuO2 xH2O-Pt/C at the cathode under a certain operating condition was studied using cyclic voltammetry, electrochemical impedance spectra (EIS) and polarization curve techniques. When the fuel cell modified with RuO2 xH2O-Pt/C was operated at lower pressure, a faster and more stable dynamic response could be found. Modifying with RuO2 xH2O-Pt/C composite material not only slightly increases the single cell performance but also dramatically improves the dynamic response performance, revealing that RuO2 xH2O-Pt/C can buffer the voltage undershoot whenever the current increases instantly.

关 键 词:PEMFC  dynamic response  RuO2 xH2O  electrodeposite
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