| 固相萃取–HPLC–ICP/MS法测定水中的烷基汞 |
| |
| 引用本文： | 杨正标,闻欣,刘晶,等.固相萃取–HPLC–ICP/MS法测定水中的烷基汞[J].化学分析计量,2014(1):39-41. |
| |
| 作者姓名： | 杨正标 闻欣 刘晶 等 |
| |
| 作者单位： | 南京市环境监测中心站,南京210013 |
| |
| 基金项目： | 南京市环保科研课题（201105） |
| |
| 摘 要： | 建立了固相萃取、高效液相色谱与电感耦合等离子体质谱联用技术测定水中烷基汞的方法。对固相萃取、高效液相色谱和电感耦合等离子体质谱的实验条件进行了优化。在优化条件下,甲基汞和乙基汞的检出限分别为0.5,0.7 ng/L。对地表水、工业废水和生活污水3种水样分别加标10.0,50.0 ng/L进行测定,测定结果的相对标准偏差为3.3%~9.6%(n=6),加标回收率在81.0%~103.0%之间。该方法灵敏度高,实用性强。
|
| 关 键 词： | 固相萃取 烷基汞 高效液相色谱–电感耦合等离子体质谱 形态分析 |
Determination of Alkylmercury in Water by HPLC-ICP/MS with Solid Phase Extraction |
| |
| Yang Zhengbiao,Wen Xin,Liu Jing,Lu Xihong,Yang Lili.Determination of Alkylmercury in Water by HPLC-ICP/MS with Solid Phase Extraction[J].Chemical Analysis And Meterage,2014(1):39-41. |
| |
| Authors: | Yang Zhengbiao Wen Xin Liu Jing Lu Xihong Yang Lili |
| |
| Institution: | (Nanjing Environmental Monitoring Center, Nanjing 210013, China) |
| |
| Abstract: | A method for determination of alkylmercury in water based on solid phase extraction and high performance liquid chromatography coupled with inductivity coupled plasma-mass spectrometry （HPLC-ICP/MS） was established. The working conditions were optimized. The detection limit was 0.5 ng/L for methylmecury and 0.7 ng/L for ethylmercury, the relative standard deviation was in the range of 3.3%-9.6%（n=6）,and the recovery ranged from 81.0%to 103%. The method is sensitive and applicable. |
| |
| Keywords: | solid phase extraction alkylmercury HPLC-ICP/MS speciation analysis |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
