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Infrared spectra of some polybasic acid triphenyltin IV derivatives
Affiliation:1. Department of Engineering and Natural Sciences, University of Applied Sciences Merseburg, Eberhard-Leibnitz-Straße 2, 06217 Merseburg, Germany;2. Department of Chemistry, Faculty of Science, University of Kragujevac, Radoja Domanovića 12, 34000 Kragujevac, Serbia;3. Department of Immunology, Institute for Biological Research “Siniša Stanković” ̶ National Institute of the Republic of Serbia, University of Belgrade, Bulevar despota Stefana 142, 11060 Belgrade, Serbia;4. Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia;5. Innovation Centre of the Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia;6. Institute of Physiology and Biochemistry “Ivan Djaja”, Faculty of Biology, University of Belgrade, Studentski trg 16, Belgrade 11000, Serbia;7. Department of Chemistry and Biochemistry, Faculty of Agriculture, University of Belgrade, Nemanjina 6, 11080 Belgrade, Serbia
Abstract:
Triphenyltin IV polybasic acid derivatives have been synthesized, and structures suggested on the basis of their IR spectra. Tetrahedral oxoanions behave as polydentate ligands giving infinite type structures. The cleavage of these infinite type structures occurs when the derivatives react with strong Lewis bases giving discrete structure adducts. A particular type of coordination of the selenite (tetradentate) has been established.
Keywords:
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