|
|||||
|
|
The thermodynamics of mixing C6 and C7 compounds with a bicyclic compound at infinite dilution |
|
| Authors: | T. M. Letcher R. Baxter |
| Affiliation: | (1) Department of Chemistry, Rhodes University, 6140 Grahamstown, South Africa |
| Abstract: | The activity coefficients at infinite dilution have been measured at 25°C for cyclohexane, cyclohexene, 1,3-cyclohexadiene, 1,4-cyclohexadiene, benzene, n-hexane, 1-hexene, 1-hexyne, n-heptane, 1-heptene and 1-heptyne in decahydronaphthalene, bicyclohexyl, 1,2,3,4-tetrahydronaphthalene and cyclohexylbenzene. These results, together with previously determined HmE and VmE have been used to calculate the partial molar excess thermodynamic properties of mixing at infinite dilution. |
| Keywords: | Activity coefficients at infinite dilution gas-liquid chromatography decalin bicyclohexyl tetralin cyclohexylbenzene C6 and C7 compounds thermodynamics of mixing partial molar volumes enthalpies, entropies and Gibbs function |
| 本文献已被 SpringerLink 等数据库收录！ | |