Nickel(II) and copper(II) complexes with an asymmetric bidentate Schiff-base ligand derived from furfurylamine |
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| Authors: | Email author" target="_blank">Aliakbar?Dehno?KhalajiEmail author Sepideh?Maghsodlou?Rad Gholamhossein?Grivani Debasis?Das |
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| Institution: | (1) Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran;(2) School of Chemistry, Damghan University, P. O. Box 36715-364, Damghan, Iran;(3) Department of Chemistry, The University of Burdwan, Burdwan, West Bengal, India |
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| Abstract: | New asymmetric bidentate Schiff-base ligand (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine, (HL), and its nickel(II) and copper(II)
complexes with the general composition ML2 M = Ni (1) and Cu (2)], were prepared. The ligand and the metal complexes were characterized by elemental analysis, FT-IR, and UV–Vis spectroscopy.
In addition, 1H-NMR and X-ray powder diffraction (XRD) were employed for characterization of ligand and metal complexes, respectively. Thermogravimetric
analysis (TGA) of the ligand and metal complexes revealed the thermal stability and decomposition pattern of the species. |
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