Molecular energetics of alkyl substituted pyridine <Emphasis Type="Italic">N</Emphasis>-oxides |
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Authors: | Joana I T A Cabral Ricardo A R Monteiro Marisa A A Rocha Luís M N B F Santos Jr" target="_blank">William E AcreeJr Maria D M C Ribeiro da Silva |
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Institution: | 1.Centro de Investiga??o em Química, Department of Chemistry, Faculty of Science,University of Porto,Porto,Portugal;2.Department of Chemistry,University of North Texas,Denton,USA |
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Abstract: | The standard (p° = 0.1 MPa) energies of combustion in oxygen, at T = 298.15 K, for the solid compounds 2-methylpyridine-N-oxide (2-MePyNO), 3-methylpyridine-N-oxide (3-MePyNO) and 3,5-dimethylpyridine-N-oxide (3,5-DMePyNO) were measured by static-bomb calorimetry, from which the respective standard molar enthalpies of formation
in the condensed phase were derived. The standard molar enthalpies of sublimation, at the same temperature, were measured
by Calvet microcalorimetry. From the standard molar enthalpy of formation in gaseous phase, the molar dissociation enthalpies
of the N–O bonds were derived, and compared with values of the dissociation enthalpies of other N–O bonds available for other
pyridine-N-oxide derivatives. |
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