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Studies on aromatic amine boranes by 11B and 1H NMR
Affiliation:1. State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;2. The Library of Qingdao Agricultural University, Qingdao, 266109, P. R. China
Abstract:
1H and 11B NMR spectroscopy was applied to mono- and bisborane adducts derived from aryl-, benzyl-, phenethyl- and phenylenediamines, but no simple relationship was established between the spectroscopic data and the nature of the NB bond. Comparative studies of the affinity of aromatic amines to BH3 by equilibria reactions may be of great value in establishing a scale of relative basicity.
Keywords:
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