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Accurate determination of the spin Hamiltonian parameters for Mn2+ ions in cubic ZnS nanocrystals by multifrequency EPR spectra analysis
Authors:Stefan M  Nistor S V  Barascu J N
Affiliation:National Institute of Materials Physics, POB MG-7, 077125 Magurele-Bucharest, Romania. mstefan@infim.ro
Abstract:
Accurate determination of the spin Hamiltonian (SH) parameters, describing the electron paramagnetic resonance (EPR) spectra of paramagnetic impurity ions in wide band gap semiconductor nanocrystals, is essential for determining their localization and quantum properties. Here we present a procedure, based on publicly available software, for determining with higher accuracy the SH parameters of isolated Mn(2+) impurity ions in small cubic ZnS nanocrystals. The procedure, which can be applied to other cubic II-VI semiconductor nanocrystals as well, is based on the analysis of both low and high frequency EPR spectra with line shape simulation and fitting computing programs, which include the hyperfine forbidden transitions and line broadening effects. The difficulties, limitations and errors which can affect the accuracy in determining some of the SH parameters are also discussed.
Keywords:
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