Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. 61. Darstellung und Kristallstruktur von Tetramethyltitan-1,2-bis(dimethylphosphino)ethan

Contributions to the Chemistry of Transition Metal Alkyl Compounds. 61. Preparation and Crystal Structure of Tetramethyltitanium-1,2-bis(dimethylphosphino)ethane The title complex 1 was synthesized by addition of 1,2-bis(dimethylphosphino)ethane to a solution of tetramethyltitanium in diethylether. The complex was characterized by ¹H, ¹³C and ³¹P NMR spectra and by X-ray crystal structure analysis. 1 consists of two independent molecules with distorted octahedral structure.