Über die Darstellung der Bis(triphenylsilyl)-sulfane (C6H5)3Si<span class='icomoon'>?Sx<span class='icomoon'>?Si(C6H5)3 (x = 3, 4) und die Kristallstruktur von (C6H5)3Si<span class='icomoon'>?S4<span class='icomoon'>?Si(C6H5)3期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Über die Darstellung der Bis(triphenylsilyl)-sulfane (C6H5)3Si?Sx?Si(C6H5)3 (x = 3, 4) und die Kristallstruktur von (C6H5)3Si?S4?Si(C6H5)3

Authors:	R. Minkwitz A. Kornath H. Preut

Abstract:	On the Preparation of Bis(triphenylsilyl)sulfanes (C₆H₅)₃Si? S_x? Si(C₆H₅)₃ (x = 3, 4) and the Crystal Structure of (C₆H₅)₃Si? S₄? Si(C₆H₅)₃ The preparation of the bis(triphenylsilyl)sulfanes Ph₃Si? S_x? SiPh₃ (x = 3, 4) from Ph₃SiSNa and SCl₂ resp. S₂Cl₂ is reported. They are characterized by vibrational, NMR and UV-VIS spectroscopic measurements. Ph₃Si? S₄? SiPh₃ crystallizes in space group P1 with a = 943.6(6) pm, b = 945.7(5) pm, c = 1 881.7(12) pm, α = 82.11(5)°, β = 78.95(5)°, γ = 83.15(5)° and Z = 2.

Keywords:	Bis(triphenylsilyl)sulfanes preparation single crystal X-ray structure vibrational spectra NMR spectra UV-VIS spectra