A manganese sulfite with extended metal–oxygen–metal bonds exhibiting hydrogen uptake |
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| Authors: | K. Prabhakara Rao A. Govindaraj C.N.R. Rao |
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| Affiliation: | aChemistry and Physics of Materials Unit, CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560064, India |
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| Abstract: | A manganese sulfite of the formula Mn5(OH)4(SO3)3·2H2O, I{a=7.5759(7) Å, b=8.4749(8) Å, c=10.852(1) Å, β=100.732(2)°, Z=2, space group=P21/m (no. 11), R1=0.0399 and wR2=0.1121 [for R indexes I>2σ(I)]}, comprising Mn3O14 units and extended Mn–O–Mn bonds along the three dimensions has been synthesized under hydrothermal conditions. It has narrow channels along the b-axis and exhibits hydrogen storage of 2.1 wt% at 300 K and 134 bar. |
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| Keywords: | Manganese sulfite Hydrothermal synthesis X-ray diffraction Metal– oxygen– metal bonds Antiferromagnetism Hydrogen storage |
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